BN-Cell

Novel BInGaN semiconductor compounds for high efficiency solar cells

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¤ The scientific profile of the project leader

The project leader, Dr. Emil Mihai Pavelescu, is a senior researcher 1st  grade (the highest rank in Romania) at the National Institute for Research and Development in Microtechnologies IMT- Bucharest since 2009 and an associate professsor at the Faculty of Exact Sciences and Engineering of Hyperion University since 2011. He has authored and co-authored over 75 publications in international and national peer-review journals and proceedings (all ISI ranked) gathering 628 citations (without selfcitations) with an h-index of 15.

After 6 months spent (under the aegis of a Romanian Governmental Fellowship earned followed a national contest) at the Microelectronics Research Group of IESL/FORTH (where he characterized by  photoluminecence  GaN-based  materials  –  an  imprtant  technique  for  the  current  proposal), Greece, he has been for 5 years with the Optoelectronics Research Center (ORC) of Tampere University of Technology including an initial 1 year Marie Curie Fellowship at the ORC.

During this stay he has been intensively involved in 2 international (MONOPLA and FAST ACCESS) and several Finnish projects dealing with growth (molecular-beam epitaxy – the key technique for the current project proposal) and characterization of III-V semiconductors and devices, especially (dilute) nitride alloys. While at ORC, he successfully introduced and applied the strain compensation/mediation  approach  to engineer the highly strain of GaInNAs/GaAs quantum well heterostructures. The results were published in Applied Physics Letters (DOI: 10.1063/1.1470223) gathering over 60 citations, based on ISI Web of Science.

The experience accumulated on this topic wil be applied to BInGaN/GaN alloys. He was also the first in the world to emphasize the key role of selfannealing  effect in optical activity of (dilute)nitride-containing devices and the subsequent publication on this finding in Applied  Physics Letter (DOI:  10.1063/1.1601309) was very well appreciated and cited over 40 times. The effects of self annealing are very important and will be taken into account in design and growth of the p-i-n GaN+/BInGaN/GaN-  solar cells, when the p-type GaN top layer is usually grown at a much higher temperature around 720 oC after deposition of the BInGaN layer at temperatures around 520 oC, to avoid strong In desorption. In parallel with developing dilute-nitride heterostructures for light emitters, he started research activity on nitrogen incorporation into GaInNAs layers lattice matched to GaAs (Journal of Applied  Physics;  DOI:
10.1063/1.2112173, 20 citations) a research which constituted the preliminary grounds of the future solar cells currently developed in ORC.

The experience in developing (growing) dilute GaInNAs alloys lattice matched to GaAs will be used in this project for developing BInGaN alloys with low B content lattice matched to GaN. At ORC, he found that the optical activity of InGaNAs/GaAsQWs improves semnificantly if the structures are electron irradiated and subsequently thermall annealed (Pavelescu et al., Appl. Phys. Lett. DOI: 10.1063/1.1834997, 15 citations).
After the ORC research stage, he has also been for 3 years with the Technological Physics group of University of Kassel as a senior researcher where he led a research group on molecular-beam epitaxy of III-V quantum dots semiconductor compounds and heterostructures. At the same time, he was involved in implementation of the European project “Brighter” and was the key member of the Kassel University research team involved in European project “DeLight”. During the work within the  “Brighter”  project,  he  realized  a  quantum  dot  laser  exhibiting  the  lowest  wavelength dependence of its lasing wavelength with temperature  without distributed feedback gratings or a Peltier cooler, which is still a worldwide record (DOI: 10.1088/0268-1242/23/8/085022).

After joining the IMT-Bucharest, he found, leading the current international project N- IBCell (Engineered group III-N-(As) alloys and low-dimensional  heterostructures for high efficiency intermediate band  solar cells) and the previously coordinated project (Development of advanced  heterostructures containing  III-N compound  semiconductors used in high efficiency solar cells), that electron irradiation and subsequent thermal annealing also remarkably improves the optical quality of GaInNAs alloys lattice matched to GaAs not only that of the strained GaInNAs/GaAs    QWs    (Pavelescu    et    al.    DOI:    10.1088/0268-1242/28/2/025020,    DOI: 10.1016/j.jlumin.2012.12.008,  DOI: 10.1016/j.jlumin.2014.05.042),  as previously found in ORC.

This finding is very important, as this technology will be applied to our BInGaN/GaN alloys to improve their optical activity. Within the N-IBCell project, he also successfully developed a p-i-n GaAs+/InAs/Ga(In)NAs/GaAs-  solar cell (Pavelescu  et al., DOI:  10.1016/j.optmat.2015.12.035), key experience for developing the proposed p-i-n GaN/BInGaN/GaN solar cells. The last but not the least, within the same project, he managed very recently (unpublished yet to be submitted to
2016 MBE conference as late news) to incorporate a record (based on our knowledge) 7.7% of B into GaN by MBE, constituting the most powerful momentum for our target of growing BInGaN layers lattice matched to GaN with boron contents ≥10%.

The 18 peer-reviewed ISI-ranked journal articles (8 as  a  main  author) published after getting the PhD without contribution of the PhD supervisor (Prof. Markus Pessa) and numerous citations (628) with a large h-index (15) of the project leader publications in ISI-ranked journal illustrates by themselves not only the independent research activity of the applicant but also its clear international visibility.

The outstanding scientific achievements  of the project leader in the last 10 years, 2006 – present

1. Articles

1.   E.-M.  Pavelescu,  V.  Polojarvi,  A.  Schramm,  A.  Tukiainen,  A.  Aho,  W.X.  Zhang,  J.Puustinen, J. Salmi, M. Guina, “Effects of insertion of strain-engineering Ga(In)NAs layers on optical properties of InAs/GaAs quantum dots for high-efficiency solar cells”, Optical Materials  Vol. 52, pp. 177-180, 2016.
2.   E.-M. Pavelescu, M. Dumitrescu, M. Guina, “Instability of structural defects generated by electron irradiation in GaInNAs quantum wells”, J. Luminescence,  Vol.154, pp. 584-586,
2014.
3. E.-M.  Pavelescu,  R.  Kudrawiec,  M.  Dumitrescu,  “On  photoluminescence  and photoreflectance of 1-eV GaInNAs-on-GaAs epilayers”, J. Luminescence, Vol. 141, pp. 67-
70, 2013.
4.   E-M. Pavelescu,  R. Kudrawiec, N. Bălţăţeanu, S. Spȃnulescu, M. Dumitrescu, M. Guina, „Enhancement  in  photoluminescence from  1  eV  GaInNAs  epilayers  subject  to  7  MeV electron irradiation”, Semicond. Sci. Technol., Vol. 28, pp. 025020, 2013.
5.   E.-M. Pavelescu, R. Kudrawiec, J. Puustinen, A. Tukiainen, M. Guina, “Effects of 7-MeV electron irradiation on photoluminescence from 1-eV GaInNAs-on-GaAs epilayers”, J. Luminescence, Vol. 136, pp. 347-50, 2013.
6.   E.-M.  Pavelescu,  C  Gilfert, P  Weinmann,  M  Danila,  A  Dinescu,  M.  Kamp  and  J.-P.Reithmaier, “1100-nm InGaAs/(Al)GaAs quantum dot lasers for high power applications”, J. Phys. D.: Appl. Phys., Vol. 44, 145104, 2011.
7.   C. Gilfert, E. M. Pavelescu, and J.P. Reithmaier, “Influence of the As2/As4 growth modes on the formation of quantum dot like InAs islands grown on InAlGaAs/InP (100)”, Appl. Phys. Lett., Vol. 96, 191903, 2010.
8.   M.  Syperek,  P.  Leszczyński,  J.  Misiewicz,  E.  M.  Pavelescu,   C.  Gilfert,  and  J.  P. Reithmaier, “Time-resolved photoluminescence spectroscopy of an InGaAs/GaAs quantum well-quantum dots tunnel injection structure“, Appl. Phys. Lett., Vol. 96, pp. 011901, 2010.
9.   E.-M.  Pavelescu,  C. Gilfert, J. P. Reithmaier, A. Martín-Mínguez, I. Esquivias, “High- power  tunnel-injection  1060-nm  InGaAs-(Al)GaAs  quantum-dot  lasers”,  IEEE  Photon.
Tech. Lett, Vol. 21, pp. 999, 2009.
10. E.  M.  Pavelescu,  J.P.  Reithmaier,  W.  Kaiser,  P.  Weinmann,  M.  Kamp,  A.  Forchel, "Wavelength stabilized quantum dot lasers for high power applications", Phys. Stat. Sol. B, Vol. 246, pp. 872, 2009.
11. E-M   Pavelescu,   C   Gilfert,  J   P   Reithmaier,  A   Martín-Mínguez   and   I  Esquivias, ‘GaInAs/(Al)GaAs  quantum-dot  lasers  with  high  wavelength  stability’  Semicond.  Sci. Technol., Vol. 23, pp. 085022, 2008.
12. E.-M. Pavelescu,  J. Slotte, V.D.S. Dhaka, K. Saarinen, S. Antohe, Gh. Cimpoca, and M. Pessa, ‘On the optical crystal properties of quantum-well GaIn(N)As/GaAs semiconductors grown by molecular-beam epitaxy’ J. Cryst. Growth, vol. 297, pp. 33-37, 2006.
13. J. Slotte, K. Saarinen, E.-M. Pavelescu,  T. Hakkarainen, and M. Pessa, ‘Nitrogen related vacancies in GaAs based quantum well superlattices’, Appl. Phys. Lett., vol. 89, pp. 061903,
2006.
14. V. Dhaka, N. Tkachenko, H. Lemmetyinen, E.-M. Pavelescu,  J. Konttinen, M. Pessa, K.Arstila,   and   J.   Keinonen,   ‘Room-temperature   self-annealing   of   heavy-ion-irradiated InGaAs/GaAs quantum wells’ Electron. Lett., vol. 41, pp. 1304-1305, 2006.

2. Books/ chapters (including monographs) :

1.   Engineered Quantum Dot Structures: Fabrication and Applications, Reithmaier, Johann Peter; Pavelescu,  Emil-Mihai;  Gilfert, Christian; et al., QUANTUM SENSING AND NANOPHOTONIC DEVICES VI Book Series: Proceedings of SPIE-The International Society for Optical Engineering Vol. 7222, 72220R, 2009. – review article
2.   Emil-Mihai  Pavelescu, “Research  and Development of Dilute Nitride Semiconductors GaInNAs-on-GaAs”, TTY-PAINO, Tampere, 2004. ISBN 952-15-1235-0, ISSN 1459-2045. - book
3.   Li, M. Pessa, T. Jouhti, C. S. Peng, and E.-M.  Pavelescu,  ‘GaInNAs quantum well lasers’, Encyclopedia  of Nanoscience and Nanotechnology,  vol. 3, pp. 719-730, 2004, ISBN: 1-58883-059-4. – book chapter
4.  W. Li, J. Konttinen, T. Jouhti, C.S. Peng, E.-M. Pavelescu, M.Suominen, M. Pessa, “Extending the emission wavelength of  GaInNAs/GaAs quantum well lasers  beyond
1300 nm”, Advanced  Nanomaterials and Nanodevice, Institute of Physics Publishing. IOP Publishing Ltd. 2003, pp. 251-260, ISBN: 0750309652, 2003. – review article
5.   Pessa, M, Peng, CS, Jouhti, T, Pavelescu, EM, Li, W, Karirinne, S, Liu, H, Okhotnikov, O,  “Long-wavelength  nitride  lasers  on  GaAs”,  MICROELECTRONIC ENGINEERING   Vol. 69   Issue: 2-4, pp. 195-207, 2003 – review article

3. Reseach projects

The project leader was involved in the following projects having as the main topic solar cells:

I. 2015-2017 Project Coordinator, national  project: “Novel III-N-Bi semiconductor compounds for high efficiency solar cells” PN-II-RU-TE 2014, http://www.imt.ro/N-BiCell/
II.  2014-2017 Project Coordinator, international project (Norwegian University of Science and Technology as partner): “Engineered group III-N-(As) alloys and low-dimensional heterostructures for high efficiency intermediate band solar cells”, EEA-RO 2009-2014 Financial Mechanism, http://www.imt.ro/N-iBCell/index_en.php. Papers published so far:

1. E.-M.  Pavelescu  et  al.,  Effects  of insertion  of strain-engineering  Ga(In)NAs layers  on optical properties     of     InAs/GaAs    quantum    dots     for     high-efficiency     solar     cells,    OPTICAL MATERIALS Volume: 52  Pages: 177-180  Published: FEB 2016
2. V. Polojarvi, E.-M. Pavelescu et al., Optical properties and thermionic emission in solar cells with     InAs     quantum     dots     embedded     within     GaNAs     and     GaInNAs,     SCRIPTA MATERIALIA Volume: 108   Pages: 122-125 Published: NOV 2015
3. E.-M.  Pavelescu  et al.,  Instability of structural  defects generated  by electron irradiation  in GaInNAs  quantum  wells,  JOURNAL  OF  LUMINESCENCE  Volume:  154    Pages:  584-586 Published: OCT 2014

III. 2010-2012 Principal Investigator (PI), national  project: “Development of advanced heterostructures containing III-N compound semiconductors used in high efficiency solar cells”, POSDRU/89/1.5/63700

1. E.-M. Pavelescu et al., On photoluminescence and photoreflectance of 1-eV GaInNAs-on-GaAs epilayers, JOURNAL OF LUMINESCENCE  Volume: 141   Pages: 67-70   Published: SEP 2013
2. E.-M. Pavelescu et al., Effects of 7-MeV electron irradiation  on photoluminescence from 1-eV GaInNAs-on-GaAs epilayers, JOURNAL OF LUMINESCENCE  Volume: 136   Pages: 347-350
Published: APR 2013
3. Pavelescu et al., Enhancement in photoluminescence from 1 eV GaInNAs epilayers subject to 7 MeV electron  irradiation,  SEMICONDUCTOR  SCIENCE  AND  TECHNOLOGY  Volume:  28, Issue: 2   Article Number: 025020   Published: FEB 2013

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¤ General data:

  • Project duration: 2017-2019
  • Project budgeti: 850 000 RON
  • Domain: Physical Sciences and Engineering
 

¤ Project coordinated by:

National Institute for Research and Development in Microtechnologies- 
IMT Bucharest
http://www.imt.ro/

General information   Contact
Project financed by PNIII, Program 4 – Basic Research and Frontier, Project type: Exploratory Research Projects, 
ID project: PN-III-P4-ID-PCE-2016-0742, 
Contract No. 180/2017.
 

National Institute for Research and Development in Microtechnologies- IMT Bucharest
Project director: Dr. Emil Mihai PAVELESCU
E-mail: emil[dot]pavelescu[at]imt[dot]ro
Tel:  +40-21-269.07.70; +40-21-269.07.74;
Fax: +40-21-269.07.72; +40-21-269.07.76;
Website: www.imt.ro

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